> If a Raspberry Pi had industrial environment ratings and was certified hard real time, then yes it could be considered a PLC.

Ostensibly yes, but so far I haven't seen anyone really use a PLC in a way that requires hard real time (so far). The cycle on eg a siemens S7-1200 is anyway much too slow for anything really exciting, and a Pi might very well be more reliable in actual practice, were it not for the very unfortunate tendency to eat SD cards. :-P

(And revolution pi actually ships a hardened Pi for industrial use. So that's one way to go about it. I'm not a big fan of that brand, but it's a data-point. Meanwhile in personal experience some regular pi's left in industrial cabinets for one-off emergency monitoring purposes have managed to stay annoyingly alive over time.)