NAS stuff can benefit greatly and straightforwardly.

A typical NVMe SSD can easily do sequential reads at 7GB/s, which outpaces a 25Gbps connection by more than 2x. NAS is more typically backed by SATA HDDs, but there's some relatively easy way to put an NVMe disk in front of them as a cache.

Do you ever _need_ it? Perhaps not, but there's plenty of common activities just stemming from NAS usage which see a linear speedup, and would continue to get faster up to 100Gbps even.