AFAIK no - in both NTSC and PAL you're transmitting a monochrome signal plus some extra analog information that encodes two additional color channels. The difference between NTSC and PAL is primarily the framerate and the color encoding method: PAL encodes color in a slightly different way (by Alternating the Phase on each Line) that's more robust to analog distortion. But it's still ultimately encoded as a color subcarrier on top of a black-and-white signal. The only relevance the 4-tube cameras have to the story is that they provided an easy and convenient way for striking camera operators to kill color.

The big sin in NTSC is the 59.94fps field rate. This is because NTSC transmitted on 6MHz channels that were fully utilized, there was no space for color. A naive implementation of this at 60hz field rate would mean beat frequencies with the audio carrier, giving visible dot patterns in the signal. Slowing down the field rate got rid of that interference.

PAL was based off an existing German 625-line system that was transmitted on wider channels, so they had extra bandwidth. No slowdown was required. But at the same time PAL was not a clean break, nor was it British. It's a German standard that applies the same general idea as NTSC[0] to German B&W. It was only a clean break in that didn't use the UK or French systems[1], which were either too low or too high resolution to be practical for 1960s color tubes.

[0] If you want to see a real sin, go take a look at the alternate history of interlaced-color TV that NTSC saved us from. NTSC is a sin in the same way that putting the Red Cross logo on a health pack in a videogame is technically a war crime.

[1] Which, to be clear, also had enough bandwidth for color without a beat frequency.