The value of employee equity is approximately zero, but sometimes people get lucky. Don't let these arguments fool you into thinking you're definitely in that 5%, because in the absence of information about the market, the product, and the other people you're working with you're probably in that 95% that makes nothing. By all means update your priors but arguments about expected value assume that all things are equal, and they are manifestly not equal.

the article takes this into account with EV

obviously vol is not the end all be all but one of your main advantages as a startup employee is access to the insider info and being able to walk away