I'm not sure if it was a deliberate omission or not, but it's worth pointing out in the Sunset model that the sky should not go black as soon as the Sun goes below the horizon as it does in the demo. The Sun will still be shining on the atmosphere above you, and in areas above your horizon for a considerable time after Sunset. There will still be a noticeable twilight (in Earth's atmosphere) until the Sun is 18 degrees below the horizon. It's probably not practical to implement using ray tracing, but there are common algorithms to model it.

Indeed that’s what twilight is by definition.