> There's no relationship between the two written variables. Stores to the two are independent and can be reordered. The aq/rel applies to the index, not to the unrelated non-atomic buffer located near the index.

No, this is incorrect. If you think there's no relationship, you don't understand "release" semantics.

https://en.cppreference.com/w/cpp/atomic/memory_order.html

> A store operation with this memory order performs the release operation: no reads or writes in the current thread can be reordered after this store.