I also went about looking at the difference rather than the order. In the hexadecimal case, the difference is 15 (0xEF vs 0x12). I thought, then, that for any base B with ascending digits A and descending digits D, (D-(B-1))/A=B-2.
For binary, it looks like (1-(b-1))/1=b-10 or (1-(2-1))/1=2-2=0 in decimal.
For trinary, it looks like (21-(b-1))/12=b-2 or (7-(3-1))/5=5/5=1 in decimal.
For quaternary, it looks like (321-(b-1))/123=b-2 or (57-(4-1))/27=54/27=2 in decimal.
Essentially and perhaps unsurprisingly, the size of the slices in the number pie get smaller the bigger the pie gets. In binary, the slice is the pie, which is why the division comes out to zero there.