The Linux man page (https://man7.org/linux/man-pages/man3/atoi.3.html#VERSIONS) says that POSIX.1 leaves it unspecified. As you found out, it's really something that should be avoided as much as possible, because pretty much everywhere disagrees how it should behave, especially if you value portability.
sscanf() is not a good replacement either! It's better to use strtol() instead. Either do what Lwan does (https://github.com/lpereira/lwan/blob/master/src/lib/lwan-co...), or look (https://cvsweb.openbsd.org/src/lib/libc/stdlib/strtonum.c?re...) at how OpenBSD implemented strtonum(3).
For instance, if you try to parse a number that's preceded by a lot of spaces, sscanf() will take a long time going through it. I've been hit by that when fuzzing Lwan.
Even cURL is avoiding sscanf(): https://daniel.haxx.se/blog/2025/04/07/writing-c-for-curl/
If your use case can have C++, then [std::from_chars][1] is ideal. Here's gcc's [implementation][2]; a lot of it seems to be handling different bases.
[1]: https://en.cppreference.com/w/cpp/utility/from_chars.html
[2]: https://github.com/gcc-mirror/gcc/blob/461fa63908b5bb1a44f12...