I haven't seen that, but I do regularly see different routing for v6 and v4, so it's not surprising that sometimes it's bad routing.

I also saw things were IPv4 was MTU 1500 and v6 was 1492 (presumably because it was 6rd and the network had a lot of PPPoE) and then ICMP needs frag was rate limited which would end up with lots of stalled communications. (It took me a long time to build it, but I have a v4/v6 mtu test site now http://pmtud.enslaves.us )

And then there's he.net tunnels which used to be pretty nice, but now get you flagged for captchas and I've seen periods of 300ms added latency, which I assume means they're being abused. I had to stop advertising the range on my lan because it caused more problems than any benefits.

If your ISP provides reasonable CPE and v6 is enabled by default, most consumer equipment will use it, and most of the high traffic sites are available via v6; I would expect poor v6 routing affects more of their customers than poor v4 routing.