You can run niri from within other DEs, but I'm unsure whether it works well for your use-case. From the docs[0]:
"You can also run niri inside an existing desktop session. Then it will open as a window, where you can give it a try. Note that this windowed mode is mainly meant for development, so it is a bit buggy (in particular, there are issues with hotkeys)."
IIRC in this case the Mod key is by default Alt instead of Super.