The current is what varies proportionally with the amount of light received.
The open-circuit voltage depends mostly on the structure of the solar cells and on the temperature. It has only a very weak (logarithmic) dependence on the amount of light received.
The voltage that you measure at the output depends on the open-circuit voltage, on the amount of light received and on the amount of current that you draw from the panel.
The maximum open circuit voltage for a solar cell is easy to estimate, because it happens at the minimum temperature for which it is designed and the maximum solar illumination. It can be exceeded only using a light concentrator that projects on the panel light collected from a much greater area.