There's definitely nuance here.
Pure oxygen puts oxidative stress on your cells. Your body can handle that just fine at 1 atm, but at elevated partial pressures the increased concentration will (quickly) overwhelm your cellular mechanics.
Underwater, the maximum operating depth for 100% O2 is 6 meters (20 feet) - which isn't very much at all. If you dive any deeper than that, you'll be at severe risk for a seizure and unconsciousness, and likely drown. (I'm simplifying, see [1].)
Which is why you don't go diving with pure O2.
However, in this case the freediver wouldn't be breathing compressed O2 gas underwater. They would've been breathing it at the surface, at 1 atm.