There are two specific places where Python is not performant. I ran some tests in a few languages and Rust and C++ came out on top, by far. I could write Rust components and access them via Python. I could also use C++ and stick with Qt. Or I could take the plunge with Rust. As this is a personal app with no other users, this is a good place to keep sharpening my skills.

Then I’d say just pick the one you are most familiar with

None of the above, not really. That's why I asked OP what got him settled on Tauri.